During operation of membrane systems, biofilms develop from the onset
and participate in the separation process as a secondary membrane. Bio
films mainly consist of bacteria, the extracellular polymer substances
- which are excreted by the cells and which immobilize these cells an
d entrap particles on the membrane surfaces. The biofilm has an hydrau
lic resistance. If this leads to an intolerable loss of performance, t
he effect is called ''biofouling'' and cleaning is needed. The assumed
action of cleaners is to remove the biofouling layer. However, in man
y cases removal of the biomass is not actually observed, although perf
ormance improves after cleaning. An explanation is that the cleaner im
proves the permeation properties of the biofilm instead of removing it
. It is shown here that the application of commercial cleaning agents
substantially affects the permeability of the matrices used to model b
iofouling. Improved performance due to redispersion of the matrix is s
mall compared to the improved performance due to increased matrix perm
eability. Formaldehyde tends to decrease biofilm permeability. Thus, t
he hydraulic characteristics of biofilms on membranes are very importa
nt for the separation process and can be improved or made worse by add
ing chemicals for cleaning and disinfection.