CHANNEL-TO-CHANNEL REARRANGEMENTS OF HOST LATTICES IN CLATHRATE CRYSTALS INDUCED BY GUEST EXCHANGE VIA GAS-SOLID CONTACTS

Authors
HAYASHI N MAZAKI Y KOBAYASHI K
Citation
N. Hayashi et al., CHANNEL-TO-CHANNEL REARRANGEMENTS OF HOST LATTICES IN CLATHRATE CRYSTALS INDUCED BY GUEST EXCHANGE VIA GAS-SOLID CONTACTS, Advanced materials, 6(9), 1994, pp. 654-656
Citations number
24
Categorie Soggetti
Material Science
Journal title
Advanced materials → ACNP
ISSN journal
09359648
Volume
6
Issue
9
Year of publication
1994
Pages
654 - 656
Database
ISI
SICI code
0935-9648(1994)6:9<654:CROHLI>2.0.ZU;2-X
Abstract
Host-lattice rearrangements in clathrates as a result of sorptive gas exchange are reported for the first time. Unlike any other clathrates, those produced by the recrystallization of bis(9-hydroxyfluoren-9-yl) thieno-[3,2-b]thiophene from ethanol and n-propanol exhibit guest-resp onsive channel-type cavities: their structure differs for the guests e thanol and propanol. The structures, lattice rearrangements and guest displacement of the system are discussed.