STUDIES ON MACROCYCLIC DITERPENOIDS .13. AN EFFICIENT TOTAL SYNTHESISOF (+ -)-SARCOPHYTOL-M/

Authors
LI YL YUE XJ
Citation
Yl. Li et Xj. Yue, STUDIES ON MACROCYCLIC DITERPENOIDS .13. AN EFFICIENT TOTAL SYNTHESISOF (+ -)-SARCOPHYTOL-M/, Synthesis, (9), 1994, pp. 913-914
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
9
Year of publication
1994
Pages
913 - 914
Database
ISI
SICI code
0039-7881(1994):9<913:SOMD.A>2.0.ZU;2-E
Abstract
The total synthesis of(+/-)-sarcophytol-M, a marine cembranol, was ach ieved from (E)-geraniol in twelve steps by using an intramolecular nuc leophilic addition of a sulfur-stabilized carbanion to a ketone as the key step.