ENTHALPIES OF MIXING FOR THE N-PENTANE PLUS METHYLACETATE PLUS DICHLOROMETHANE SYSTEM AT 298.15 K AND THEIR PREDICTION WITH THE UNIFAC MODEL

Citation
Il. Acevedo et al., ENTHALPIES OF MIXING FOR THE N-PENTANE PLUS METHYLACETATE PLUS DICHLOROMETHANE SYSTEM AT 298.15 K AND THEIR PREDICTION WITH THE UNIFAC MODEL, Thermochimica acta, 241, 1994, pp. 95-102
Citations number
15
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00406031
Volume
241
Year of publication
1994
Pages
95 - 102
Database
ISI
SICI code
0040-6031(1994)241:<95:EOMFTN>2.0.ZU;2-X
Abstract
New experimental data of the excess molar enthalpies at 298.15 K for t he ternary system n-pentane + methylacetate + dichloromethane, togethe r with corresponding data for the constituent binary mixtures, are pre sented. Different expressions from the literature are used to predict excess enthalpies from the corresponding binary data. The empirical co rrelation of Nagata and Tamura (J. Chem. Eng. Data, 33 (1988) 283) giv es the best results for this system. The UNIFAC group contribution is applied to predict ternary excess molar enthalpies which are compared with the experimental data.