Il. Acevedo et al., ENTHALPIES OF MIXING FOR THE N-PENTANE PLUS METHYLACETATE PLUS DICHLOROMETHANE SYSTEM AT 298.15 K AND THEIR PREDICTION WITH THE UNIFAC MODEL, Thermochimica acta, 241, 1994, pp. 95-102
New experimental data of the excess molar enthalpies at 298.15 K for t
he ternary system n-pentane + methylacetate + dichloromethane, togethe
r with corresponding data for the constituent binary mixtures, are pre
sented. Different expressions from the literature are used to predict
excess enthalpies from the corresponding binary data. The empirical co
rrelation of Nagata and Tamura (J. Chem. Eng. Data, 33 (1988) 283) giv
es the best results for this system. The UNIFAC group contribution is
applied to predict ternary excess molar enthalpies which are compared
with the experimental data.