Ion beam technologies provide a variety of well-proven means for creat
ing or enhancing strong, stable, direct adhesion of thin films deposit
ed on substrates. Interface chemical bonding and structure are critica
l. Yet success with such approaches has been reported for a great vari
ety of systems that have little or no bulk chemical affinity, includin
g metals, polymers, ceramics, and semiconductors. This review paper de
scribes the established techniques of reactive and nonreactive ion bea
m sputtering, ion-beam-assisted deposition, ion implantation, and ion
beam stitching. It then presents representative examples of adhesion e
nhancement selected from the current literature, in order to clarify t
he roles of interface chemistry, morphology, contaminants, and stabili
ty. The review offers a basis upon which interface tailoring for adhes
ion may be planned in order to optimize both performance and fabricati
on of specific materials systems.