Mossbauer spectroscopy and x-ray diffraction were employed to investig
ate the magnetic and structural properties of the high-pressure monocl
inic phase of magnetite. Measurements were performed to 66 GPa at 300
K using diamond anvil cells. Based primarily upon the Mossbauer parame
ters, the following features of the high-pressure phase were deduced.
With increasing pressure the high-pressure phase evolves at P greater-
than-or-equal-to 25 GPa and its abundance increases monotonically at t
he expense of the low-pressure cubic phase. The high-pressure phase is
not magnetic at 300 K and its monoclinic structural features resemble
that of the low-pressure phase. The tetrahedral and octahedral sites
characteristic of the inverse spinel structure, albeit distorted, rema
in the building blocks of the high-pressure phase. The fast electron h
opping between Fe3+ and Fe2+ at the octahedral sites prevails to the h
ighest pressure. It is suggested that the cubic --> monoclinic --> cub
ic hysteretic cycle involves a mild displacive phase transition not af
fecting the coordination number of any of the iron cations.