The Luttinger-Kohn canonical transformations are used to derive the ef
fective band Hamiltonian for a quantum well. The transformations produ
ce 8-function potentials in the effective-mass approximation. The boun
dary conditions on envelope functions, obtained from this effective Ha
miltonian, differ from the BenDaniel-Duke ansatz. The effective Hamilt
onian depends on the electronic coherence length. It also has a veloci
ty-dependent term that is proportional to the sum of band lineup energ
ies.