High quality, completely relaxed Ge films have been grown on Si(111) u
sing Sb as surfactant at the initial stage of growth. After desorbing
the surface Sb layer, cusplike reflection high-energy electron diffrac
tion intensity oscillations indicated excellent Ge layer-by-layer epit
axy. High resolution x-ray diffraction analysis showed a very high cry
stalline quality and well resolved thickness fringes consistent with a
flat relaxed Ge layer. Chemical preferential etching experiments reve
aled a defect density of down to approximately 3 X 10(4) cm-2.