NOVEL DEOXYGENATIVE ACYLATION OF DIARYL KETONES WITH ACYLSILANES MEDIATED BY LANTHANOID METALS

Authors
TANIGUCHI Y NAGAFUJI A MAKIOKA Y TAKAKI K FUJIWARA Y
Citation
Y. Taniguchi et al., NOVEL DEOXYGENATIVE ACYLATION OF DIARYL KETONES WITH ACYLSILANES MEDIATED BY LANTHANOID METALS, Tetrahedron letters, 35(37), 1994, pp. 6897-6898
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
37
Year of publication
1994
Pages
6897 - 6898
Database
ISI
SICI code
0040-4039(1994)35:37<6897:NDAODK>2.0.ZU;2-Z
Abstract
The reaction of diaryl ketones and benzoyltrimethylsilane is mediated by lanthanoid metals such as ytterbium to give the deoxygenatively acy lated product, I,I-diarylacerophenones in good yields. In the reaction with acetylsilane, the corresponding silyl enol ether was obtained in a moderate yield.