INTRAMOLECULAR ALDER ENE APPROACH TO STEREOCHEMICAL CONTROL OVER 3 CONTIGUOUS STEREOGENIC CENTERS - SYNTHESIS OF (+ -)-METHYL CUCURBATE AND(+/-)-METHYL EPIJASMONATE/

Authors
SARKAR TK GHORAI BK BANERJI A
Citation
Tk. Sarkar et al., INTRAMOLECULAR ALDER ENE APPROACH TO STEREOCHEMICAL CONTROL OVER 3 CONTIGUOUS STEREOGENIC CENTERS - SYNTHESIS OF (+ -)-METHYL CUCURBATE AND(+/-)-METHYL EPIJASMONATE/, Tetrahedron letters, 35(37), 1994, pp. 6907-6908
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
37
Year of publication
1994
Pages
6907 - 6908
Database
ISI
SICI code
0040-4039(1994)35:37<6907:IAEATS>2.0.ZU;2-#
Abstract
The total synthesis of epijasmonoids, (+/-)-methyl cucurbate and (+/-) -methyl epijasmonate is described starting from aldehyde 14, where the key step is a highly stereocontrolled 5- (3,4) ene cyclization 17 --> 18.