NONIDEALITY IN ISOTOPIC MIXTURES

Authors
JANSCO G REBELO LPN VANHOOK WA
Citation
G. Jansco et al., NONIDEALITY IN ISOTOPIC MIXTURES, Chemical Society reviews, 23(4), 1994, pp. 257-264
Citations number
35
Categorie Soggetti
Chemistry
Journal title
Chemical Society reviews → ACNP
ISSN journal
03060012
Volume
23
Issue
4
Year of publication
1994
Pages
257 - 264
Database
ISI
SICI code
0306-0012(1994)23:4<257:NIIM>2.0.ZU;2-8
Abstract
Although widely considered to be ideal solutions, mixtures of isotopic ally substituted molecules (e.g. CH4 and CD4) show small but significa nt deviations from ideality. This review discusses the experimental de termination of non-ideality in solutions of isotopomers and their theo retical interpretation, including the molecular origins of the effect.