Six shallow donors are shown to form in Czochralski silicon deliberate
ly doped with hydrogen during the early stages of heat treatment at 35
0-degrees-C. The ground state energies of five of these donors are alt
ered slightly in material doped with deuterium rather than hydrogen, d
emonstrating the presence of hydrogen in their cores. One of the donor
s may account for some of the weak IR absorption features detected in
as-grown material. The formation of these donors appears to be linked
to the generation of the well known oxygen-related double thermal dono
rs and may reflect the partial passivation of these latter defects.