The removal efficiency of intermittently applied pesticides by a granu
lar activated carbon bed preloaded with background organic matter (BOM
) was examined using the rapid small-scale column test. Preloading wit
h BOM decreased the removal efficiency of the pesticides. The removal
efficiency was a function of the amount of BOM adsorbed, but was unrel
ated to the influent concentration of the pesticide. A modeling approa
ch employing the ideal adsorbed solution theory and a linear driving-f
orce expression for intraparticle surface diffusion adequately simulat
ed these phenomena.