A new series of biologically active oxovanadium(V) complexes of benzot
hiazolines derived from heterocyclic ketones and 2-mercaptoaniline wer
e synthesized and characterized by elemental analyses, molecular weigh
t determinations and conductance measurements. Spectroscopic studies i
ndicate coordination of sulphur and the azomethine nitrogen to the met
al. All the free ligands and their complexes have been tested in vitro
against a variety of pathogenic fungi and bacteria and were found to
possess appreciable fungicidal and bactericidal properties.