J. Li et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW ALKALINE-EARTH METAL CHALCOGENIDE - BARIUM DITELLURIDE, Materials research bulletin, 29(10), 1994, pp. 1041-1048
During our exploration of kinetically stable solid state materials, we
have discovered a new binary material, BaTe2, the first alkaline eart
h metal dichalcogenide prepared using flux growth technique. The cryst
al structure of BaTe2 was determined by single-crystal X-ray diffracti
on methods. It belongs to the tetragonal space group I4/mcm (No. 140)
with lattice constants a = 7.181(1)angstrom, c = 8.898(2)angstrom, V =
458.8(1)angstrom3 and Z=4. The final residual index is converged to R
=1.5%, wR2=3.5%. BaTe2 is a Zintl type compound isostructural to SrS2.
Pairs of tellurium atoms form dimeric units (Te2)2- with a Te-Te sepa
ration of 2.7722(8) angstrom. The synthesis of BaTe2 at relatively low
temperature has provided an alternative and convenient route for prep
aring new compounds in this category.