Jc. Salasmorales et Jw. Evans, FURTHER-STUDIES OF A ZINC AIR CELL EMPLOYING A PACKED-BED ANODE .3. IMPROVEMENTS IN CELL DESIGN, Journal of Applied Electrochemistry, 24(9), 1994, pp. 858-862
A laboratory-scale zinc-air cell described previously has been redesig
ned with the intention of improving its performance. The zinc was pres
ent as a packed bed of 600 mum particles and in this concept the elect
rolyte and particles are replaced with fresh ones at the end of discha
rge, permitting the use of a monofunctional air electrode. The improve
d design had a reduced electrolyte volume on the air side of the cell
and better electrical connection to the bed of particles, along with m
ore conveniently located conduits for electrolyte flow driven by natur
al convection. When discharged at room temperature under the Simplifie
d Federal Urban Driving Schedule (SFUDS) regimen (modified to eliminat
e regenerative braking) the cell yielded energies that were 2.8 times
higher than the original cell (Part I). Increasing the cell temperatur
e (up to 55-degrees-C) was found to bring further improvements. Natura
l convection was shown to be necessary for good cell performance.