COPPER(I) NITRATE PI-COMPLEXES, SYNTHESIS AND CRYSTAL-STRUCTURE OF THE 1ST CUNO3 PI-COMPLEX WITH DIALLYLAMINE OF EQUIMOLAR COMPOSITION

Authors
MYSKIV MG GORESHNIK EA PECHARSKII VK OLIJNIK VV
Citation
Mg. Myskiv et al., COPPER(I) NITRATE PI-COMPLEXES, SYNTHESIS AND CRYSTAL-STRUCTURE OF THE 1ST CUNO3 PI-COMPLEX WITH DIALLYLAMINE OF EQUIMOLAR COMPOSITION, Journal of structural chemistry, 35(1), 1994, pp. 82-86
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
35
Issue
1
Year of publication
1994
Pages
82 - 86
Database
ISI
SICI code
0022-4766(1994)35:1<82:CNPSAC>2.0.ZU;2-D
Abstract
We have carried out synthesis and X-ray structural study (DARCH, MoK(a lpha) radiation, graphite monochromator, theta/2theta scan mode, 2thet a less-than-or-equal-to 65-degrees) of the CuNO3.C6H11N pi-complex (a = 14.346(6), c = 16.719(7) angstrom, space group 14(1)/a, and Z = 16). The bifunctional (bridge and chelate) tridentate molecule of diallyla mine cross-links the inorganic component into infinite spirals oriente d along the axes 4(1) and 4(3). The mainly covalent character of the C u+ ...NO3- bond affects the hydrogen bond strength and the efficiency of the metal-olefin interaction.