One of the challenges facing both regulators and the regulated communi
ty in dealing with air toxic emissions and their control, is the need
to accurately measure and characterize these emissions. The current te
chnology for measuring metallic components in emission streams require
s manual sample extraction, recovery and preservation of the sample, a
nd finally analysis of the sample using laboratory instrumentation. Wh
ile these techniques are capable of analyzing trace concentrations of
metals with adequate accuracy and precision, they all have numerous dr
awbacks due to their complexity and the fact that they do not provide
real-time data. This paper describes two programs that ADA Technologie
s has undertaken to develop measurement technology for toxic metals in
combustion flue gas. These research programs are directed at overcomi
ng limitations of the current state-of-the-art measurement systems in
order to meet the needs for accurate and reliable monitoring of toxic
metal emissions from stationary sources. Both programs focus on the de
velopment of instrumentation for the detection and quantization of tra
ce levels of air toxic metals in combustion gas environments. The inst
ruments are being designed to function as continuous, real-time, on-li
ne analyzers that can serve as parts of a feedback process to control
air toxic metals emissions.