ASYMMETRIC OXIDATION OF D-GLYCERALDEHYDE DIETHYL DITHIOACETAL WITH A SHARPLESS REAGENT

Authors
GOMEZ YA SASTRE JAL AMO JFR TEJEDOR MAS
Citation
Ya. Gomez et al., ASYMMETRIC OXIDATION OF D-GLYCERALDEHYDE DIETHYL DITHIOACETAL WITH A SHARPLESS REAGENT, Journal of carbohydrate chemistry, 13(7), 1994, pp. 1051-1058
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology
Journal title
Journal of carbohydrate chemistry → ACNP
ISSN journal
07328303
Volume
13
Issue
7
Year of publication
1994
Pages
1051 - 1058
Database
ISI
SICI code
0732-8303(1994)13:7<1051:AOODDD>2.0.ZU;2-P
Abstract
The asymmetric oxidation reaction of D-glyceraldehyde diethyl dithioac etal 1 and its di-O-acetyl derivative with a Sharpless reagent to prod uce the corresponding D-glyceraldehyde diethyl dithioacetal S-oxide de rivatives takes place with high stereoselectivity. The configuration o f the two new chiral centres formed is deduced.