K. Matsuda et al., MORPHOLOGY OF A PLANER PRECIPITATE AND IT S ORIENTATION RELATIONSHIP TO THE MATRIX IN AN AL-1.0 MASS-PERCENT-MG2SI-0.4 MASS-PERCENT-SI ALLOY, Nippon Kinzoku Gakkaishi, 58(3), 1994, pp. 252-259
The morphology of planer precipitates and the orientation relationship
s between the precipitates and the matrix in an Al-1.0 mass%Mg2Si-0.4
mass%Si alloy were investigated by transmission electron microscopy (T
EM). Some equilateral triangular precipitates and many polygonal preci
pitates were observed by a scanning electron microscope. TEM observati
on of the precipitates and the extracted precipitates from the matrix
by thermal phenol method shows that the equilateral triangular precipi
tates are thin plates. The electron diffraction patterns taken from th
ese precipitates were analyzed as a silicon that has a diamond structu
re (a = 0.543 nm). Energy dispersive X-ray spectroscopic (EDS) analysi
s measured at the extracted precipitates showed only Si peak. Some str
aight boundaries exist in the equilateral triangular precipitate. It w
as observed by high resolution electron microscopy that the boundaries
are plane defects such as stacking faults. Electron diffraction spots
taken from this precipitate show the forbidden reflection. Such spots
are caused by stacking faults. Therefore, the equilateral triangular
precipitate is silicon. Orientation relationships between the precipit
ate and the matrix is as follows; (001)Alparallel-to (111)Si and the a
ngle between [100]Al and [1BAR10]Si is 10 degrees. Three sides of the
triangular Si precipitate are parallel to the direction of [110]Si in
(111)Si.