G. Mattausch et al., GLASSY PROPERTIES OF THE RELAXOR FERROELECTRIC STRONTIUM BARIUM NIOBATE AT LOW-TEMPERATURES, Phase transitions, 59(4), 1996, pp. 189-223
Relaxer ferroelectrics are known to show a low-temperature behaviour t
hat quantitatively resembles the features of canonical glasses. In ord
er to get a comprehensive characterisation of the responsible low-ener
gy excitations, single crystals of strontium barium niobate were inves
tigated below 10 K. The density of localised states was obtained from
heat capacity, and their coupling to phonons from sound velocity and t
hermal conductivity. The presence of slowly relaxing systems could be
estimated from heat release data, respectively. In contrast with struc
tural glasses, however, SBN and further relaxer ferroelectrics show an
energy dependent density of states and an upper limit of the relaxati
on time spectrum. Considering these properties, which appear to be typ
ical also for other glassy crystals, a modification of the standard tu
nneling model is proposed.