The charge properties of an MOS structure based on n-type 6H-SiC have
been studied at room temperature. An insulating layer 30 nm thick was
grown under the gate by thermal oxidation of epitaxial 6H-SiC with a (
0001)Si orientation (the concentration of uncompensated donors was 2.8
X 10(16) cm(-3)) in a flow of dry oxygen with an admixture of trichlo
roethylene vapor. The breakdown voltage of the oxide measured under el
ectron-accumulation conditions ranges up to 25 V. The breakdown field
is 8 x 10(6) V/cm. Under conditions of a pronounced nonequilibrium dep
letion, the MOS structures withstand voltages up to 300-350 V. This re
sult indicates that a layer with an inverted p-type conductivity forms
at an extremely low rate at the SiO2/SiC interface. The small-signal
admittance of the MOS structure is analyzed at frequencies of 1 kHz an
d 1 MHz. The density of surface states is found to have an exponential
energy distribution within the 6H-SiC band gap near the conduction ba
nd. The total density of states is N-t similar or equal to 2 x 10(11)
cm(-2). The surface charge density fixed in the oxide is N-f similar o
r equal to 10(11) cm(-2). Surface traps with levels near the conductio
n band are classified as acceptor-like (the cross section for electron
capture is -similar to 10(-18) cm(-2)).