M. Wintz et al., HOT CRACKING DURING SOLIDIFICATION OF STE EL - EFFECT OF CARBON, SULFUR AND PHOSPHORUS, Revue de métallurgie, 91(1), 1994, pp. 105-114
Segregated internal cracks in continuous casting are dependent for the
ir formation on both technological parameters of casting and physical-
chemistry properties of steels. In this study, we focussed our attenti
on upon the relations between solidification and hot cracking phenomen
a. Solidification development in series of carbon manganese steels was
studied using quenched metal samples which had undergone solidificati
on in a positive thermal gradient. Three series of carbon manganese st
eels with respectively variable sulphur, phosphorus and carbon content
s were studied. Sulphur and phosphorus segregations in the liquid are
important at the end of solidification. For instance, the ratio of max
imum concentration of phosphorus to minimum concentration is around 16
. This value is very large compared with the one's measured for mangan
ese (1.9) and silicon (1.4). Hot cracking interval, deduced from solid
ification study, increase with carbon, sulphur and phosphorus contents
. Fracture criteria for different steel grades were determined by bend
ing test performed on ingots (300 kg) during solidification. Sulphur c
ontent appears to have a stronger effect on cracking threshold drop. E
xploitation of a model concerning thermomechanical behaviour of produc
t during solidification permitted to obtain billet stress charts. The
obtained results verify that segregated internal cracks in billets are
found preferably near the angles. The presence of sulphur and phospho
rus enhances the width of the brittleness region inside the mushy zone
.