Poly(vinyl alcohol) is considered as a potential material in thin-laye
r 'all solid' batteries. By adding an appropriate doping agent, intrin
sic ionic conduction is observed leading to its use as a solid electro
lyte in zinc/halogen and zinc/metal oxide batteries. The association o
f zinc metal powder and conjugated salt in poly(vinyl alcohol) leads t
o a composite anode which acts as a proton generator or protode when t
he system is a proton conductor.