We provide a new estimate of the long-distance component to the radiat
ive transition B-->rho gamma. Our mechanism involves the soft scatteri
ng of on-shell hadronic products of nonleptonic B decay, as in the cha
in B-->rho rho-->rho gamma. We employ a phenomenological fit to scatte
ring data to estimate the effect. The specific intermediate states con
sidered here modify the B-->rho gamma decay rate at roughly the 5-8% l
evel, although the underlying effect has the potential to be larger. C
ontrary to other mechanisms of long distance physics which have been d
iscussed in the literature, this yields a non-negligible modification
of the B-0-->rho(0) gamma channel and hence will provide an uncertaint
y in the extraction of V-td. This mechanism also affects the isospin r
elation between the rates for B--->rho(-)gamma and B-0-->rho(0) gamma
and may generate CP asymmetries at experimentally observable levels.