1-ACYLOXY-2(1H)-PYRIMIDINE-2-THIONES AS NOVEL RADICAL PRECURSORS

Authors
LIEBSCHER J RIEMER B BENDIG J STOSSER R
Citation
J. Liebscher et al., 1-ACYLOXY-2(1H)-PYRIMIDINE-2-THIONES AS NOVEL RADICAL PRECURSORS, Tetrahedron letters, 35(38), 1994, pp. 7009-7012
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
38
Year of publication
1994
Pages
7009 - 7012
Database
ISI
SICI code
0040-4039(1994)35:38<7009:1ANRP>2.0.ZU;2-H
Abstract
Reaction of 3-isothiocyanato-2-propeniminium perchlorates 1 with hydro xylamine gives 1-hydroxy-2(1H)-pyrimidine-2-thiones 2 which can be O-a cylated. The resulting 1-acyloxy-2(1H)-pyrimidine-2-thiones 4 are nove l precursors for organic radicals. Their photochemical homolysis is st udied and affords disulfides 5, 2-alkylthiopyrimidines 6 and alkanes 7 and 8.