SILICA-GEL SUPPORTED ZIRCONOCENE DICHLORIDE METHYLALUMOXANE CATALYSTSFOR ETHYLENE POLYMERIZATION - EFFECTS OF HETEROGENATION ON ACTIVITY, POLYMER MICROSTRUCTURE AND PRODUCT MORPHOLOGY

The system zirconocene dichloride/methylalumoxane was supported on sil ica in order to provide ethylene polymerization catalysts for suspensi on or gas phase processes. Highest activity was found for a sandwich-l ike, three layer anchoring of the zirconium centers on the support sur face. The new catalyst systems show a decrease of activity compared to polymerization experiments in homogeneous phase. However, the molecul ar weights are increased and the weight distributions remain narrow by immobilization of the active catalyst sites. Those supported metalloc ene catalysts could find application for the synthesis of polyethylene materials with controlled rheology.