NEW CERIUM NITRIDE CHLORIDES - CE6CL12N2 AND CENCL

Authors
EHRLICH GM BADDING ME BRESE NE TRAIL SS DISALVO FJ
Citation
Gm. Ehrlich et al., NEW CERIUM NITRIDE CHLORIDES - CE6CL12N2 AND CENCL, Journal of alloys and compounds, 206(1), 1994, pp. 95-101
Citations number
6
Categorie Soggetti
Chemistry Physical","Metallurgy & Mining","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
206
Issue
1
Year of publication
1994
Pages
95 - 101
Database
ISI
SICI code
0925-8388(1994)206:1<95:NCNC-C>2.0.ZU;2-U
Abstract
The compound CeNCl is shown to be isotypic with tetragonal BiOCl with lattice parameters a = b = 4.079(2) angstrom, c = 6.837(2) angstrom. T he compound Ce6Cl12N2 was prepared from CeCl3, Ce and NaN3 in a sealed Nb tube at 750-degrees-C. The structure of Ce6Cl12N2 was solved by X- ray single crystal diffraction and shown to contain edge-shared, nitro gen-centered, cerium tetrahedra. The lattice parameters for Ce6Cl12N2 were determined to be a = 11.233(4) angstrom, b = 16.527(8) angstrom, c = 10.708(3) angstrom, beta = 90.15-degrees in the spacegroup P2(1)/c .