The empirical pseudopotential method within the virtual crystal approx
imation is used to calculate the band structure of Mg1-xZnySySe1-y, wh
ich has recently been proved to be a potential semiconductor material
for optoelectronic device applications in the blue spectral region. It
is shown that MgZnSSe can be a direct or an indirect semiconductor de
pending on the alloy composition. Electron and hole effective masses a
re calculated for different compositions. Polynomial approximations ar
e obtained for both the energy gap and the effective mass as functions
of alloy composition at the GAMMA valley. This information will be us
eful for the future design of blue wavelength optoelectronic devices a
s well as for assessment of their properties.