STUDIES TOWARDS THE SYNTHESIS OF ESPERAMICINONE

Authors
CLARK DA DERICCARDIS F NICOLAOU KC
Citation
Da. Clark et al., STUDIES TOWARDS THE SYNTHESIS OF ESPERAMICINONE, Tetrahedron, 50(39), 1994, pp. 11391-11426
Citations number
66
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
39
Year of publication
1994
Pages
11391 - 11426
Database
ISI
SICI code
0040-4020(1994)50:39<11391:STTSOE>2.0.ZU;2-M
Abstract
A strategy is presented for the synthesis of esperamicinone (3), the a glycone of esperamicin A(1). The route is based on an asymmetric epoxi dation of a quinone monoketal. Two approaches for the installation of the vinylogous urethane are described.