The effect of application of liming material (CaCO3 or CaSiO3) and pho
sphate, on pH, exchangeable Al, effective cation exchange capacity (EC
EC) and P solubility is studied in several variable-charge soils of vo
lcanic origin from Canary Island (Spain). The amendments were added to
replace 1.5 X or 2.5 X exchangeable Al, and P was applied at rates to
provide equilibrium solution concentrations of 1 mg l(-1). Incubation
of the samples with P, had very little or no effect on pH and on the
exchangeable Al content of the soils. When P and amendments were combi
ned, exchangeable Al levels declined with no concomitant effect on pH.
Phosphate application alone produced a small increase in the effectiv
e cation exchange capacity (ranging from 0.2 to 16.1 mmol(c) kg(-1)).
This effect being much more marked when liming materials were previous
ly added. Prior addition of CaCO3 did not produce any effect on soluti
on P, irrespective of the exchangeable Al content of the soils. On the
contrary, in some of the soils CaSiO3 treatment increased P concentra
tion in solution.