K. Matsuda et al., ULTRASONIC EFFECTS ON ELECTROORGANIC PROCESSES .1. PRODUCT-SELECTIVITY IN ELECTROREDUCTION OF BENZALDEHYDES, Chemistry Letters, (9), 1994, pp. 1619-1622
Ultrasonic irradiation to electroorganic systems resulted in significa
nt effects on product-selectivity in the reduction of benzaldehydes an
d others. By the irradiation, the selectivity of reduction products fo
rmed by consuming fewer electrons was drastically enhanced. The effect
s were rationalized as due to not cavitation but agitation of electrol
ytic solutions by ultrasonic waves.