SYNTHESIS AND STRUCTURE OF NOVEL ORGANO(SILOXO)PLATINUM COMPLEXES - FACILE REDUCTION BY DIHYDROGEN

Authors
FUKUOKA A SATO A MIZUHO Y HIRANO M KOMIYA S
Citation
A. Fukuoka et al., SYNTHESIS AND STRUCTURE OF NOVEL ORGANO(SILOXO)PLATINUM COMPLEXES - FACILE REDUCTION BY DIHYDROGEN, Chemistry Letters, (9), 1994, pp. 1641-1644
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1994
Pages
1641 - 1644
Database
ISI
SICI code
0366-7022(1994):9<1641:SASONO>2.0.ZU;2-9
Abstract
Novel mono- and dinuclear organo(siloxo)platinum complexes PtR(OSiPh(3 ))(cod) (R = Me, Ph) and [{PtMe(cod)O}Ph(2)Si]O-2 have been prepared a nd characterized. The molecular structure of PtPh(OSiPh(3))(cod) has b een determined by X-ray structure analysis. The activity for reduction of PtMe(OSiPh(3))(cod) and PtMe(OPh)(cod) by H-2 is higher than that of PtMe(2)(cod).