PI-CONJUGATED CHARGE-TRANSFER POLYMER CONSTITUTED OF ELECTRON-DONATING THIOPHENE AND ELECTRON-WITHDRAWING QUINOXALINE

Authors
YAMAMOTO T KANBARA T OOBA N TOMARU S
Citation
T. Yamamoto et al., PI-CONJUGATED CHARGE-TRANSFER POLYMER CONSTITUTED OF ELECTRON-DONATING THIOPHENE AND ELECTRON-WITHDRAWING QUINOXALINE, Chemistry Letters, (9), 1994, pp. 1709-1712
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1994
Pages
1709 - 1712
Database
ISI
SICI code
0366-7022(1994):9<1709:PCPCOE>2.0.ZU;2-3
Abstract
Palladium-catalyzed polycondensation between 2,5-bis(trimethyl-stannyl )thiophene and 5,8-dibromoquinoxaline derivatives gives soluble new pi -conjugated polymers, which exhibit absorption bands at 575 +/- 30 nm assignable to intramolecular charge transfer bands and show the three- photon resonant third-order nonlinear optical susceptibility chi((3)) of about 5 X 10(-11) esu.