A NOVEL AND REGIOSELECTIVE RADICAL CYCLIZATION OF GEM-DIHALOCYCLOPROPYL SUBSTITUTED ALKENES AND ALKYNES USING TRIBUTYLTIN HYDRIDE AND CATALYTIC AIBN

Authors
TANABE Y NISHII Y WAKIMURA K
Citation
Y. Tanabe et al., A NOVEL AND REGIOSELECTIVE RADICAL CYCLIZATION OF GEM-DIHALOCYCLOPROPYL SUBSTITUTED ALKENES AND ALKYNES USING TRIBUTYLTIN HYDRIDE AND CATALYTIC AIBN, Chemistry Letters, (9), 1994, pp. 1757-1760
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1994
Pages
1757 - 1760
Database
ISI
SICI code
0366-7022(1994):9<1757:ANARRC>2.0.ZU;2-J
Abstract
Various gem-dihalocyclopropyl substituted alkenes and alkynes were tra nsformed into the corresponding bicyclo[3.1.0]- or [4.1.0] compounds w ith high regioselectivity through a reductive radical cyclization usin g tributyltin hydride in the presence of catalytic azobisisobutyronitr ile (AIBN).