2ND-HARMONIC GENERATION FROM THE MONOLAYERS OF RARE-EARTH COMPLEXES ET(2)NC(6)H(4)CH=CHC(5)H(4)NC(16)H(33)LN(TTA)(4) (LN=LA,ND,DY,YB)

Authors
WANG KZ JIANG W HUANG CH XU GX XU LG LI TK ZHAO XS XIE XM
Citation
Kz. Wang et al., 2ND-HARMONIC GENERATION FROM THE MONOLAYERS OF RARE-EARTH COMPLEXES ET(2)NC(6)H(4)CH=CHC(5)H(4)NC(16)H(33)LN(TTA)(4) (LN=LA,ND,DY,YB), Chemistry Letters, (9), 1994, pp. 1761-1764
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1994
Pages
1761 - 1764
Database
ISI
SICI code
0366-7022(1994):9<1761:2GFTMO>2.0.ZU;2-9
Abstract
The LB films of four hemicyanine salts with rare earth complex anions were prepared. From second-harmonic generation experiments, the second -order molecular hyperpolarizability beta was evaluated to be about 2X 10(-27) e.s.u. Enhanced second-order nonlinearity compared with the he micyanine bromide was discussed according to the crystal structure of a model complex. The results of UV -Vis, IR and low angle X-ray diffra ction for the LB films are also reported.