Dvs. Jain et Ns. Dhar, A SEMIEMPIRICAL MODEL FOR PREDICTING EXCESS-ENTHALPIES OF ALKYLBENZENE MIXTURES, Journal of the Indian Chemical Society, 70(4-5), 1993, pp. 481-484
A semi-empirical model for predicting excess enthalpies of alkylbenzen
e mixtures is presented. The method treats alkylbenzene molecule as co
nsisting of three types of surfaces, i.e. aromatic, C6H5, and aliphati
c, CH3 and CH2, and considers three interaction parameters characteris
ing interaction between aromatic-aliphatic, aromatic-aromatic and alip
hatic-aliphatic surfaces. The model is also able to predict DELTAH(v)
of alkylbenzenes.