S. Moorbath et al., EXTREME ND-ISOTOPE HETEROGENEITY IN THE EARLY ARCHEAN - FACT OR FICTION - CASE-HISTORIES FROM NORTHERN CANADA AND WEST GREENLAND, Chemical geology, 135(3-4), 1997, pp. 213-231
Sm-Nd data on rock suites from early Archaean provinces in northern Ca
nada and West Greenland clearly demonstrate that tectonothermal (i.e.
igneous, metamorphic, tectonic) processes which affected the rocks lon
g after their formation produced open-system behaviour leading to effe
ctive resetting of the Sm-Nd system accompanied by complete, or near-c
omplete, Nd-isotope homogenisation. This means that extreme caution is
required in interpreting highly variable initial epsilon(Nd) values o
f ancient rocks in terms of long-standing regional mantle heterogeneit
y or of complex mantle-crust interaction processes. In particular, cal
culated initial epsilon(Nd), values based on high-precision zircon U-P
b dates may be of little or no significance in terms of geochemical ev
olution of early mantle and crust source regions. A striking example i
s provided by the Acasta gneisses of northern Canada, with published S
HRIMP U-Pb zircon dates in the range 3.6-4.0 Ga and apparent, initial
epsilon(Nd) values in the range -4.8 to +3.6 (Bowring and Housh, 1995)
. A combination of 34 published and new Sm-Nd whole-rock analyses for
a wide range of rock types yields a regression (errorchron) age of 337
1 +/- 59 Ma (MSWD = 9.2), with initial epsilon(Nd) = -5.6 +/- 0.7. Whi
lst the very negative initial epsilon(Nd) provides strong, independent
support for the extreme age of the Acasta gneiss protolith, resetting
of the Sm-Nd system at similar to 3.4 Ga renders calculation of initi
al epsilon(Nd) based on the zircon U-Pb dates geologically meaningless
. Analogous considerations for early Archaean Akilia enclaves and host
Amitsoq gneisses of West Greenland suggest that their published range
of initial epsilon(Nd) values of similar to -4.5 to +4.5 at similar t
o 3.73-3.87 Ca (Bennett et al., 1993) may be unrealistically wide and,
therefore, inappropriate for modelling upper-mantle heterogeneity. In
an attempt to determine a realistic initial epsilon(Nd) value, we hav
e regressed 58 published and new Sm-Nd data for two major rock units o
f the Isua supracrustal belt (felsites and mica-schists), regarded as
having a short-term crustal history combined with minimal Sm-Nd distur
bance. The Sm-Nd regression yields an age of 3776 +/- 52 Ma (MSWD = 8.
2), with initial epsilon(Nd) = +2.0 +/- 0.6 This value is much closer
to conventional depleted-mantle models (e.g., DePaolo et al., 1991) th
an to the value of similar to +4.5 proposed by Bennett et al. (1993) f
or this age range. Our observations suggest that there may have been n
o major change in processes between early Archaean and more recent sty
les of depleted-mantle evolution.