INTERNAL-ROTATION ANALYSIS OF THE GROUND-STATE MICROWAVE-SPECTRUM OF 2-IODOPROPENE

Citation
J. Gripp et H. Dreizler, INTERNAL-ROTATION ANALYSIS OF THE GROUND-STATE MICROWAVE-SPECTRUM OF 2-IODOPROPENE, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 49(3), 1994, pp. 497-502
Citations number
24
Categorie Soggetti
Chemistry Physical",Physics
ISSN journal
09320784
Volume
49
Issue
3
Year of publication
1994
Pages
497 - 502
Database
ISI
SICI code
0932-0784(1994)49:3<497:IAOTGM>2.0.ZU;2-C
Abstract
The ground state microwave spectrum of 2-iodopropene has been reinvest igated using Fourier transform microwave spectroscopy. The barrier hin dering methyl internal rotation could be obtained from narrow splittin gs of high-J lines. In addition an improved hyperfine structure and ce ntrifugal distortion analysis resulted in refined constants and an app roximate determination of the iodine spin-rotation coupling parameters .