CRYSTAL-STRUCTURE OF TRIPHENYLTIN 3-(1,3-BENZODIOXOL-5-YL)-PROPENOATE

Authors
NG SW DAS VGK
Citation
Sw. Ng et Vgk. Das, CRYSTAL-STRUCTURE OF TRIPHENYLTIN 3-(1,3-BENZODIOXOL-5-YL)-PROPENOATE, Zeitschrift fur Kristallographie, 209(9), 1994, pp. 742-743
Citations number
14
Categorie Soggetti
Crystallography
Journal title
Zeitschrift fur Kristallographie → ACNP
ISSN journal
00442968
Volume
209
Issue
9
Year of publication
1994
Pages
742 - 743
Database
ISI
SICI code
0044-2968(1994)209:9<742:COT3>2.0.ZU;2-8
Abstract
Triphenyltin 3-(1,3-benzodioxol-5-yl)-propenoate (triphenyltin beta-pi peronylacrylate) adopts a carboxylate-bridged helical chain structure with the tin atom in a trans-trigonal bipyramidal geometrical environm ent. The two tin-oxygen bond distances (Sn - O = 2.234(2) angstrom, Sn < -O = 2.246(2) angstrom) are not significantly different, implying s ignificant covalent character in the bridge.