A BINUCLEAR SILVER COMPLEX OF A TETRAPYRAZOLYL LIGAND

Authors
CLEGG W COOPER PJ LOCKHART JC RUSHTON DJ
Citation
W. Clegg et al., A BINUCLEAR SILVER COMPLEX OF A TETRAPYRAZOLYL LIGAND, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 383-386
Citations number
39
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
3
Pages
383 - 386
Database
ISI
SICI code
0108-2701(1994)50:<383:ABSCOA>2.0.ZU;2-D
Abstract
Silver(I) nitrate forms a binuclear complex with the potentially multi dentate ligand '''-tetrakis(1-pyrazolylmethyl)-1,2-ethanediamine, lyl- kappaN2-methyl)-1,2-ethanediamine]-disilver(I) dinitrate, [Ag2(C18H241 0)]2NO3. Each Ag ion is linearly coordinated by two pyrazole N2 atoms. The aliphatic amine N atoms of the ligand play no primary coordinatio n role. The two Ag ions are separated by 3.1599 (9) angstrom. There ar e additional weak interactions with the nitrate anions.