X. Ling et al., ANODE SLIME BEHAVIOR IN A LABORATORY-SCALE COPPER ELECTROREFINING PROCESS, Canadian journal of chemical engineering, 72(4), 1994, pp. 683-694
Combining conventional electrochemical measurements, laser-based visua
lization and digital image processing, the movement of anode slime, it
s spatial distribution and path of falling during the copper electrore
fining process were investigated in a laboratory scale cell. Two types
of anode slime, small agglomerates and fine particles were observed.
The behaviour of the slime was found to be closely related to the elec
trolyte circulation pattern. Different circulation rates and direction
can only change the magnitude of the falling rate of small agglomerat
es, but not its direction. The path of falling is essentially random.
By contrast, the direction of circulation can change both the rate of
movement and the direction in the case of fine-particle slimes. Downwa
rd circulation accelerates the rate of settling; the higher the circul
ation rate, the faster the rate of slime removal from the cell.