SYNTHESIS AND STRUCTURE OF TRIS[N,N-DIETHYL N'-DIPHENOXYTHIOPHOSPHORYL THIOUREATO COPPER(I)], (CU-I[C6H5O)(2)P(S)NC(S)N(C2H5)(2)])(3) - AN AGGREGATE CONTAINING A [CU3S6] NUCLEUS

Authors
HERRMANN E RICHTER R CHAU NTT
Citation
E. Herrmann et al., SYNTHESIS AND STRUCTURE OF TRIS[N,N-DIETHYL N'-DIPHENOXYTHIOPHOSPHORYL THIOUREATO COPPER(I)], (CU-I[C6H5O)(2)P(S)NC(S)N(C2H5)(2)])(3) - AN AGGREGATE CONTAINING A [CU3S6] NUCLEUS, Zeitschrift fur anorganische und allgemeine Chemie, 623(3), 1997, pp. 403-408
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
3
Year of publication
1997
Pages
403 - 408
Database
ISI
SICI code
0044-2313(1997)623:3<403:SASOTN>2.0.ZU;2-#
Abstract
A reduction of copper(II) to copper (I) occurs in the reaction of N,N- diethyl-N'-diphenooxythiophosphoryl thiourea (C6H5O)(2)P(S)-NH-C(S)-N( C2H5) with Cu2+ in presence of ethanol, and the trinuclear, neutral, d iamagnetic chelate complex {Cu-I[(C6H5O)(2)P(S)NC(S)N(C2H5)(2)]}(3) is yielded in form of colourless othorhombic crystals (a = 18.588 Angstr om, b = 25.875 Angstrom, c = 24.881 Angstrom). the lipophilically wrap ped polyion aggregate contains a [Cu3S6] nucleus with trigonal planar coordinated copper(I).