PREPARATION OF TETRAMETHYLAMMONIUM BISTRI FLUORMETHOXYBROMATE(I) (CH3)(4)N-)(BR(CF3O)(2)()

Authors
MINKWITZ R BROCHLER R
Citation
R. Minkwitz et R. Brochler, PREPARATION OF TETRAMETHYLAMMONIUM BISTRI FLUORMETHOXYBROMATE(I) (CH3)(4)N-)(BR(CF3O)(2)(), Zeitschrift fur anorganische und allgemeine Chemie, 623(3), 1997, pp. 487-490
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
3
Year of publication
1997
Pages
487 - 490
Database
ISI
SICI code
0044-2313(1997)623:3<487:POTBF(>2.0.ZU;2-J
Abstract
We describe the preparation and characterization of (CH3)(4)N+Br(CF3O) (2)(-). It is prepared via comproportionation of CF3OCl with (CH3)(4)N +BrCl2- under formation of Cl-2 at -70 degrees C, respectively via add ition elimination reaction of CF3OCl with (CH3)(4)N+Br- at -70 degrees C. The thermolabile salt is characterized by i.r., Raman, F-19, C-13 NMR and mass spectroscopy.