PECULIARITIES OF THE INTERACTION OF POLYACRYLONITRILE WITH BASIC SOLVENTS DURING HEAT-TREATMENT

Authors
PLATONOVA NV KLIMENKO IB
Citation
Nv. Platonova et Ib. Klimenko, PECULIARITIES OF THE INTERACTION OF POLYACRYLONITRILE WITH BASIC SOLVENTS DURING HEAT-TREATMENT, Russian journal of applied chemistry, 66(3), 1993, pp. 546-551
Citations number
25
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
66
Issue
3
Year of publication
1993
Part
2
Pages
546 - 551
Database
ISI
SICI code
1070-4272(1993)66:3<546:POTIOP>2.0.ZU;2-F
Abstract
An approach is proposed to understanding the nature of chromaticity of polyacrylonitrile (PAN) solutions thermally treated at 140-degrees-C in dimethylformamide (DMFA) (and films), which is based on the idea of complexes forming between molecules of the basic solvent and the poly mer functional groups modified by the solvent. Manifestation of these structures is registered in electronic spectra as absorption bands wit hin the visible wave band. Stated are the general results of the the e ffect of some basic reactants on the change in PAN structure, includin g heat treatment.