RUTHENIUM(II) COMPLEXES OF 3,4-DIMETHYLPHOSPHACYMANTRENE

Authors
BRUNET L MERCIER F RICARD L MATHEY F
Citation
L. Brunet et al., RUTHENIUM(II) COMPLEXES OF 3,4-DIMETHYLPHOSPHACYMANTRENE, Polyhedron, 13(17), 1994, pp. 2555-2561
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
17
Year of publication
1994
Pages
2555 - 2561
Database
ISI
SICI code
0277-5387(1994)13:17<2555:RCO3>2.0.ZU;2-Z
Abstract
A series of RuCl2 complexes of 3,4-dimethylphosphacymantrene (L) have been synthesized. Their structures were established on the basis of H- 1, C-13, P-31 NMR and IR spectroscopy. Two of them, trans-[RuCl2(L)4] and cis,cis,trans-[RuCl2(CO)2(L)2] were characterized by X-ray crystal structure analysis, and show the ligands L to bond via normal P-Ru si gma bonds, with Ru-P distances in the range 2.288(1)-2.339(1) angstrom .