Australia is now an important gold producer in the world. The nature o
f Australian gold production is briefly reviewed and the hydrometallur
gy of gold extraction is considered. The choice of processing routes f
or free milling, complex and refractory ores is discussed. For free mi
lling ores, cyanidation and recovery by the Carbon-in-Pulp/Carbon-in-L
each process (CIP/CIL) is the primary and proven treatment process. Co
pper containing ores are discussed in some detail as they interfere in
the CIP/CIL process. Oxygen consuming and preg-robbing ores are also
described. Five different classes of process options for pretreating r
efractory ores are considered in detail. These options include: ultraf
ine grinding; acid and alkaline pressure oxidation; and a variety of c
hemical pretreatments such as: Activox process, HMC process and Electr
olytic oxidation process. In Australia, the two pre-eminent options fo
r refractory gold ore pretreatment are roasting and biooxidation and t
his development is reported. The trial of pressure cyanidation of stib
nite concentrates at the Golden Spec mine in Australia is described. P
yrolysis, the Nitrox/Redox process, the Artech/Cashman process and the
Caro's acid process have not gained commercial status so far. The pot
ential for resin-in-pulp (RIP) to replace CIP/CIL is discussed. The us
e of cyanide has generated environmental concerns because of its toxic
ity and therefore research on alternative gold recovery processes usin
g non-toxic reagents is considered. The key candidates are: ammoniacal
thiosulphate, thiourea and halide solutions. The chemistry of these l
eaching, systems is briefly described and proposed flowsheets are refe
renced. The future prospect for biohydrometallurgical gold recovery is
indicated.