ELECTROLYTIC FORMATION OF TECHNETIUM COMPLEXES WITH PI-ACCEPTOR LIGANDS

Authors
CERDA F KREMER C GAMBINO D KREMER E
Citation
F. Cerda et al., ELECTROLYTIC FORMATION OF TECHNETIUM COMPLEXES WITH PI-ACCEPTOR LIGANDS, Journal of radioanalytical and nuclear chemistry, 186(4), 1994, pp. 291-301
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
186
Issue
4
Year of publication
1994
Pages
291 - 301
Database
ISI
SICI code
0236-5731(1994)186:4<291:EFOTCW>2.0.ZU;2-2
Abstract
Electrolytic reduction of pertechnetate was performed in aqueous solut ion containing pi-acceptor ligands. Cyanide and 1,10-phenanthroline we re the selected ligands. In both cases, electrolyses produced a cathod ic TcO2 deposit and soluble Tc complexes. When cyanide was the ligand, the complexes formed were [Tc(CN)6]5- and [TcO2(CN)4]3-. When working with the amine, [Tc(phen)3]2+ and another positively charged species were found after reaction. Results are compared with previous studies with amines, and the usefulness of the electrolytic route to obtain Tc complexes is evaluated.