THE MECHANISM OF OXYGEN INCORPORATION INTO THE PRODUCTS OF ACROLEIN OXIDATION OVER H3PMO12O40 AND K3PMO12O40

Authors
POPOVA GY ANDRUSHKEVICH TV BONDAREVA VM ZAKHAROV II
Citation
Gy. Popova et al., THE MECHANISM OF OXYGEN INCORPORATION INTO THE PRODUCTS OF ACROLEIN OXIDATION OVER H3PMO12O40 AND K3PMO12O40, Kinetics and catalysis, 35(1), 1994, pp. 80-83
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
35
Issue
1
Year of publication
1994
Pages
80 - 83
Database
ISI
SICI code
0023-1584(1994)35:1<80:TMOOII>2.0.ZU;2-0
Abstract
The mechanism of oxygen incorporation into the products of acrolein ox idation over H3PMo12O40 and K3PMo12O40 is studied. It is shown that ac rylic acid and carbon oxides are formed by a redox mechanism. Higher r ates of acrylic-acid formation on reduced heteropolycompounds are acco unted for by different mechanisms of acrolein activation on oxidized a nd reduced surfaces.