P. Quevauviller et al., CERTIFIED REFERENCE MATERIALS FOR THE QUALITY-CONTROL OF FLUORINE IN COAL, FLY-ASH AND CLAY, Fresenius' journal of analytical chemistry, 350(3), 1994, pp. 101-108
A group of laboratories has worked in various intercomparisons in the
frame of the BRC-programme (European Commission) to improve their meth
ods for fluorine determination, especially for coal analysis. These ex
ercises allowed to detect and remove sources of error. Methods were im
proved to such an extent that the certification of fluorine and chlori
ne in different materials could be envisaged and the BCR consequently
decided to produce coal, fly ash and clay materials certified for thei
r F content. In addition, chlorine was certified in the fly ash CRM.